Poly-acrylic Acid Brushes and Adsorbed Proteins
نویسندگان
چکیده
منابع مشابه
Patterned biofunctional poly(acrylic acid) brushes on silicon surfaces.
Protein patterning was carried out using a simple procedure based on photolithography wherein the protein was not subjected to UV irradiation and high temperatures or contacted with denaturing solvents or strongly acidic or basic solutions. Self-assembled monolayers of poly(ethylene glycol) (PEG) on silicon surfaces were exposed to oxygen plasma through a patterned photoresist. The etched regio...
متن کاملSynthesis of dense poly(acrylic acid) brushes and their interaction with amine-functional silsesquioxane nanoparticles.
Poly(acrylic acid) polyelectrolyte brushes were synthesized by surface-initiated atom transfer radical polymerization (SI-ATRP) of tert-butyl acrylate on planar gold surfaces and subsequent hydrolysis. Three types of monolayers with different numbers of thiol binding sites per initiating unit were used. The binding strength to the gold surface turned out to be of crucial importance for the form...
متن کاملHysteretic memory in pH-response of water contact angle on poly(acrylic acid) brushes.
We investigated the pH-dependent response of flat polyacid brushes of varying length and dispersity in the extended brush regime. Our model system consisted of poly(acrylic acid) brushes, which change from hydrophobic and neutral at low pH to hydrophilic and negatively charged at high pH, synthesized on silicon substrates using a grafting-from approach at constant grafting density. We observed ...
متن کاملZwitterionic Poly(amino acid methacrylate) Brushes
A new cysteine-based methacrylic monomer (CysMA) was conveniently synthesized via selective thia-Michael addition of a commercially available methacrylate-acrylate precursor in aqueous solution without recourse to protecting group chemistry. Poly(cysteine methacrylate) (PCysMA) brushes were grown from the surface of silicon wafers by atom-transfer radical polymerization. Brush thicknesses of ca...
متن کاملSynthesis of pH Sensitive Hydrogels Based on Poly Vinyl Alcohol and Poly Acrylic Acid
In this research, hydrogels based on poly vinyl alcohol and poly acrylic acid blend were prepared which were cross-linked by applied thermal conditions. Afterward, effects of time and heating on water uptake were investigated. The highest water uptake value exhibited by the sample that was heated for 20 min. at 110 ºC was about 2129% after 4 days at equilibrium state. Hydrogels exhibited p...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Zeitschrift für Physikalische Chemie
سال: 2015
ISSN: 2196-7156,0942-9352
DOI: 10.1515/zpch-2014-0540